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Homogeneous catalysis for unreactive bond activation / edited by Dr. Zhang-Jie Shi, professor of chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, China.

Contributor(s): Material type: TextTextPublisher: Hoboken, New Jersey : Wiley, 2014Description: 1 online resourceContent type:
  • text
Media type:
  • computer
Carrier type:
  • online resource
ISBN:
  • 9781118788998
  • 1118788990
  • 9781118789032
  • 1118789032
  • 9781118788981
  • 1118788982
  • 1118452232
  • 9781118452233
  • 9781322214696
  • 1322214697
Subject(s): Genre/Form: Additional physical formats: Print version:: Homogeneous catalysis for unreactive bond activation.DDC classification:
  • 541/.395 23
LOC classification:
  • QD505
Other classification:
  • SCI013040 | SCI013050 | SCI013000
Online resources:
Contents:
Title Page; Copyright; Preface; Contributors; Chapter 1: Catalysis In C-Cl Activation; 1.1 Introduction; 1.2 Reductive Dechlorination; 1.3 Formation of C-C Bonds; 1.4 Formation of C-N Bonds; 1.5 Formation of C-O Bonds; 1.6 Formation of C-S Bonds; 1.7 Formation of C-B Bonds; 1.8 Conclusion and Outlook; References; Chapter 2: Homogeneous Transition-Metal-Catalyzed C-F Activation; 2.1 Background; 2.2 Transition-Metal-Mediated Cross-Coupling Reactions byC-F Bond Activation; 2.4 Transition-Metal-Promoted Dehydrofluorination by C-F Bond Activation
2.5 The Applications of C-F Activation in Organic Synthesis2.6 Summary and Outlook; References; Chapter 3: Homogeneous Transition-Metal Catalyzed C-N Activation; 3.1 Background; 3.2 Palladium-Catalyzed C-N Activation; 3.3 Ruthenium-Catalyzed C-N Activation; 3.4 Nickel-Catalyzed C-N Activation; 3.5 Copper-Catalyzed C-N Activation; 3.6 Iron-Catalyzed C-N Activation; 3.7 Other-Transition-Metal-Catalyzed C-N Activation; 3.8 Computationally and Experimentally Mechanistic Studies; 3.9 Summary and Outlook; References; Chapter 4: Catalytic Carbon-Sulfur Bond Activation and Transformations
4.1 Background4.2 C-S Bond Activation by Transition Metal Compounds; 4.3 Catalytic C-S Cleavage in Thioesters; 4.4 Catalytic C-S Cleavage in Dithioacetals; 4.5 Diverse Catalytic C-S Cleavage; 4.6 Summary and Outlook; References; Chapter 5: Homogeneous Transition-Metal-Catalyzed C-O Bond Activation; 5.1 Introduction; 5.2 Palladium-Catalyzed C-O Bond Activation; 5.3 Nickel-Catalyzed C-O Bond Activation; 5.4 Other-Transition-Metal-Catalyzed C-O Bond Activation; 5.5 Summary and Outlook; References; Chapter 6: Homogeneous Transition-Metal-Catalyzed C-H Bond Functionalization; 6.1 Overview
6.2 Mechanism of C-H Cleavage6.3 Directed C-H Oxidation; 6.4 Hydroarylation; 6.5 Direct Arylation; 6.6 Carbonylation; 6.7 Hydroacylation; 6.8 Alkane Dehydrogenation; 6.9 Borylation and Silylation; 6.10 Summary and Outlook; References; Chapter 7: Catalysis in C-C Activation; 7.1 Introduction: Importance and Challenges in C-C Activation; 7.2 C-C Activation of Strained Molecules; 7.3 C-C Activation of Unstrained Molecules; 7.4 Summary and Perspective; References; Index; End User License Agreement
Summary: "This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters cover key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon"-- Provided by publisher.
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Includes bibliographical references and index.

"This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters cover key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon"-- Provided by publisher.

Machine generated contents note: Preface Contributor List Chapter 1: Catalysis in C-Cl Activation Zhong-Xia Wang and Wang-Jun Guo Chapter 2: Homogeneous Transition-metal Catalyzed C-F Activation Shang-Dong Yang Chapter 3: Homogeneous Transition-metal Catalzyed C-N Activation Xiao-Bing Wan Chapter 4: Catalytic Carbon-Sulfur Bond Activation and Transformations Zhengkun Yu Chapter 5: Homogeneous Transition-Metal-Catalzyed C-O Bond Activation Da-Gang Yu, Shuang Luo, Fei Zhao, and Zhang-Jie Shi Chapter 6: Homogeneous Transition-Metal-Catalyzed C-H Bond Functionalization Bi-Jie Li and Zhang-Jie Shi Chapter 7: Catalysis in C-C Activation Hu Li and Zhang-Jie Shi.

Print version record and CIP data provided by publisher.

Title Page; Copyright; Preface; Contributors; Chapter 1: Catalysis In C-Cl Activation; 1.1 Introduction; 1.2 Reductive Dechlorination; 1.3 Formation of C-C Bonds; 1.4 Formation of C-N Bonds; 1.5 Formation of C-O Bonds; 1.6 Formation of C-S Bonds; 1.7 Formation of C-B Bonds; 1.8 Conclusion and Outlook; References; Chapter 2: Homogeneous Transition-Metal-Catalyzed C-F Activation; 2.1 Background; 2.2 Transition-Metal-Mediated Cross-Coupling Reactions byC-F Bond Activation; 2.4 Transition-Metal-Promoted Dehydrofluorination by C-F Bond Activation

2.5 The Applications of C-F Activation in Organic Synthesis2.6 Summary and Outlook; References; Chapter 3: Homogeneous Transition-Metal Catalyzed C-N Activation; 3.1 Background; 3.2 Palladium-Catalyzed C-N Activation; 3.3 Ruthenium-Catalyzed C-N Activation; 3.4 Nickel-Catalyzed C-N Activation; 3.5 Copper-Catalyzed C-N Activation; 3.6 Iron-Catalyzed C-N Activation; 3.7 Other-Transition-Metal-Catalyzed C-N Activation; 3.8 Computationally and Experimentally Mechanistic Studies; 3.9 Summary and Outlook; References; Chapter 4: Catalytic Carbon-Sulfur Bond Activation and Transformations

4.1 Background4.2 C-S Bond Activation by Transition Metal Compounds; 4.3 Catalytic C-S Cleavage in Thioesters; 4.4 Catalytic C-S Cleavage in Dithioacetals; 4.5 Diverse Catalytic C-S Cleavage; 4.6 Summary and Outlook; References; Chapter 5: Homogeneous Transition-Metal-Catalyzed C-O Bond Activation; 5.1 Introduction; 5.2 Palladium-Catalyzed C-O Bond Activation; 5.3 Nickel-Catalyzed C-O Bond Activation; 5.4 Other-Transition-Metal-Catalyzed C-O Bond Activation; 5.5 Summary and Outlook; References; Chapter 6: Homogeneous Transition-Metal-Catalyzed C-H Bond Functionalization; 6.1 Overview

6.2 Mechanism of C-H Cleavage6.3 Directed C-H Oxidation; 6.4 Hydroarylation; 6.5 Direct Arylation; 6.6 Carbonylation; 6.7 Hydroacylation; 6.8 Alkane Dehydrogenation; 6.9 Borylation and Silylation; 6.10 Summary and Outlook; References; Chapter 7: Catalysis in C-C Activation; 7.1 Introduction: Importance and Challenges in C-C Activation; 7.2 C-C Activation of Strained Molecules; 7.3 C-C Activation of Unstrained Molecules; 7.4 Summary and Perspective; References; Index; End User License Agreement

Physical Science